US scientists improve photoresponsivity in solar perovskite by 250%

Researchers led by the University of Rochester claim to have increased the photoresponsivity of a lead-halide perovskite for solar cell applications by 250%. They created a perovskite film with a plasmonic substrate made of hyperbolic metamaterial and characterized it with transition dipole orientation.

February 21, 2023 Emiliano Bellini

Interaction between a perovskite material (cyan) and a substrate of metal-dielectric material

Image: Chloe Zhang, University of Rochester

From pv magazine Global

Scientists led by the University of Rochester in New York state have considerably reduced electron recombination processes in lead-halide perovskites (LHPs) used for solar cell applications. Recombination can have a significant impact on electrical performance in perovskite cells, with implications for open-circuit voltage, short-circuit current, fill factor, and ultimately, power conversion efficiency.

The researchers used what they call a “physics-based method” to create a film based on a type of LHP known as methylammonium lead iodide (MAPbI3). They deposited that directly on a plasmonic substrate made of hyperbolic metamaterial (HMM) with a high local density of state, via spin coating. They fabricated the multi-layered HMM with four pairs of alternative 10 nm thick layers made of silver, aluminum sulfate, and ozone (Ag-Al2 O3) by electron beam evaporation.

“The metal layer serves as a mirror, which creates reversed images of electron-hole pairs, weakening the ability of the electrons to recombine with the holes,” the scientists said, noting that they used a momentum-resolved imaging technique to characterize the film’s transition dipole orientation, which is the key factor enabling control over exciton recombination processes.

They claim that the interaction between the in–plane dipole of the LHP and its image formed on plasmonic substrate results in a tenfold decrease in the recombination rate, without any chemical treatment, optical cavity, and photonic band–gap engineering.

“Furthermore, image dipole interaction enables us to substantially improve the device performance of photodetectors by achieving more than 250% increase in the photoresponsivity,” they added.

The academics presented their findings in “Gigantic suppression of recombination rate in 3D lead-halide perovskites for enhanced photodetector performance,” which was recently published in Nature Photonics.

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